Application of intermolecular interactions on catalysis, dynamic combinatorial chemistry, and fuels for molecular machines Line of research Weak molecular interactions (hydrogen bonding, metal coordination, ion-dipole interactions and the like) are at the basis of supramolecular chemistry. These interactions are used in our laboratory in the development and control of systems under thermodynamic control (dynamic combinatorial chemistry).We also apply supramolecular interactions to the study of chemical fuels for molecular machines. Part of our work is devoted to the design and development of selective supramolecular catalysts based on nonheme iron complexes for hydrocarbon oxidation. Research lines Di Stefano Staff Supervisor: Stefano Di StefanoDepartment staff: Osvaldo LanzalungaAndrea LapiPaola D'AngeloGiorgio Olivo Publications Fast transimination in organic solvents in the absence of proton and metal catalysts. A key to imine metathesis catalyzed by primary amines under mild conditions Supramolecular Recognition Allows Remote, Site-SelectiveC-H Oxidation of Methylenic Sites in Linear AminesCoupling of the Decarboxylation of 2-Cyano-2-phenylpropanoic Acid to Large-Amplitude Motions: A Convenient Fuel for an Acid–Base-Operated Molecular SwitchRing-Opening Metathesis Polymerization of a Diolefinic [2]- Catenane−Copper(I) Complex: An Easy Route to PolycatenanesFormation of Imidazo[1,5‑a]pyridine Derivatives Due to the Action of Fe2+ on Dynamic Libraries of IminesStatistical Ring Catenation under Thermodynamic Control: Should the Jacobson−Stockmayer Cyclization Theory Take into Account Catenane Formation?Abiotic Chemical Fuels for the Operation of Molecular MachinesPredictable selectivity in remote C-H oxidation of steroids: analysis of substrate binding modeCoupled X‑ray Absorption/UV−vis Monitoring of Fast Oxidation Reactions Involving a Nonheme Iron−Oxo ComplexVariations in the Fuel Structure Control the Rate of the Back and Forth Motions of a Chemically Fuelled Molecular Switch Collaborations National collaborations: Cacciapaglia Roberta (CNR-IMC)Gianfranco Ercolani (Università degli Studi di Roma Tor Vergata)Alessandro Casnati (Università di Parma)Laura Baldini (Università di Parma)Franco Uguzzoli (Università di Parma)International collaborations: Professor Christopher A Hunter, Cambridge UKProfessor E. W. Meijer, Eindhoven NEProfessor Miquel Costas, Girona ES Fundings and awards Fundings: MIUR, PRIN 2010CX2TLM; Ricerca Universitaria Anno: 2011 - prot. C26A1174B4 (8'000,00 euro); Anno: 2012 - prot. C26A12NA8J (2'000,00 euro); Anno: 2013 Finanziamento di dipartimento (2'500,00 euro); Anno 2014: Ateneo 2014 (5'000,00 euro). Advisor for Beaumont Italia srl “Contoterzi” contract 2017-2019 (15'000,00 euro)Anno 2018: Grande Progetto Universitario (54'800,00 euro). Anno 2019 :Finanziamento Universitario 2019 (4'000,00 euro); Anno 2020: Finanziamento Universitario 2020 (15'000,00 euro)Awards: Premio alla ricerca "Chimica Organica nei suoi Aspetti Metodologici" anno 2020 assegnato dalla Divisione di Chimica Organica della Società Chimica Italiana per studi riguardanti la Chimica Organica Fisica. Theme and ERC Theme: Life-Sciences chemistryERC: PE4_12 Chemical reactions: mechanisms, dynamics, kinetics and catalytic reactionsPE5_16 Supramolecular chemistryPE5_17 Organic chemistry Traineeship offer Course of study (advised): ChemistryNotes: La disponibilità dell' internato viene valutata volta per volta attraverso un colloquio diretto con il richiedente (tirocinante o laureando magistrale) valutando le esigenze del laureando e del gruppo.