Reactivity and properties of radicals and radical ions Line of research Study of the reactivity and properties of oxygen centred radicals (aminoxyl and alkoxyl radicalsi) and radical cations of aromatic compounds with a special attention to their role in oxidative processes of synthetic interest promoted by chemical, enzymatic and biomimetic oxidants. Staff Supervisor: Osvaldo LanzalungaDepartment staff: Andrea LapiStefano Di StefanoGiorgio Olivo Publications Importance of π-Stacking Interactions in the Hydrogen Atom Transfer Reactions from Activated Phenols to Short-Lived N-Oxyl RadicalsAerobic Oxidation of 4-Alkyl-N,N-dimethylbenzylamines Catalyzed by N-Hydroxyphthalimide: Protonation-Driven Control over RegioselectivityStructural Effects on the C–S Bond Cleavage in Aryl tert-Butyl Sulfoxide Radical CationsHydrogen Atom Transfer (HAT) Processes Promoted by the Quinolinimide-N-oxyl Radical. A Kinetic and Theoretical StudyN-Demethylation of N,N-Dimethylanilines by the Benzotriazole N-Oxyl Radical: Evidence for a Two-Step Electron Transfer−Proton Transfer Mechanism Collaborations National collaborations: Prof. Massimo Bietti, Università di Roma "Tor Vergata"Dr. Michela Salamone, Università di Roma "Tor Vergata"Prof. Marco Lucarini, Università di BolognaInternational collaborations: Prof. Miquel Costas, Università di Girona, SpagnaProf. Gino A. Di Labio, University of Kelowna, British Columbia, Canada Fundings and awards Fundings: Non-heme iron complexes as efficient and versatile catalysts of oxidative processes - Progetto di ricerca grande di Ateneo 2017Effetti strutturali e del mezzo sui processi di trasferimento di atomo di idrogeno /HAT) promossi da amminossil radicali - Progetto di ricerca piccolo di Ateneo 2018 Theme and ERC Theme: Sustainable chemistryERC: PE4_12 Chemical reactions: mechanisms, dynamics, kinetics and catalytic reactionsPE5_13 Homogeneous catalysisPE5_17 Organic chemistry Traineeship offer Area di ricerca: Organic chemistryAvailability: two positionsCourse of study (advised): Chemistry
